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IB HL Chemistry Notes

by
EJ
Anions

May 05, 2025

Non-metal forms gain electrons as they have a high effective nuclear charge.

Cations

May 05, 2025

Metal atoms lose electrons.

Group 14

May 05, 2025

- Does not readily form ions (Except lead and silver). Have four valence electrons -> energetically unfavourable to lose or gain four electrons to achieve a noble gas configuration.

Covalent Character

May 05, 2025

- Ions with a charge greater than 3+ due to large charge density.
- polarise negative ions

Polyatomic Ion

May 05, 2025

- The charge can be deduced from the number of hydrogens in the formula of the corresponding acid.
E.g HNO3 charge of nitrate = -1
H2CO3 charge of carbonate = -2

- Covalent bonding

Ionic compounds

May 06, 2025

- Lattice structure
- Held by ionic bond
- Involves a fixed arrangement of ions based on repeating UNIT/UNIT CELL (not molecules).
- No fixed number of ions so formulas are rations of ions present.
- Has a coordination number
- Electrically neutral -> Total net charge 0

Lewis formula

May 06, 2025

Pairs of electrons are arranged so that each atom gains a full valence shell.

Resonance structure

May 07, 2025

- Deduce how many by looking at the number of possible positions for its double bond(s).
- Lone pairs are not drawn as delocalised (no fix position).

Resonance energy

May 07, 2025

the difference in energy between the actual molecule and a hypothetical structure with localized bonds.

e.g benzene theoretical = -362 kJ/mol

Experimental = -210 kJ/mol

resonance energy = -210--362= 152kJ/mol

Lewis forumula with formal charges

May 07, 2025

FC = V - (0.5B + L)

If structures have the same difference of formal charge. A negative charge on the more electronegative atom is more stable.

Hybrid orbitals

May 07, 2025

Overlap of a hybrid orbital with any other atomic orbital always forms a sigma bond.

Transition metals magnetic property

May 09, 2025

Every electron spin acts as a tiny magnet. When the electron is unpaired the net magnetic effect is not canceled out.